Combination of interfacial reduction of hexavalent chromium and trivalent chromium immobilization on tin-functionalized hydroxyapatite materials
نویسندگان
چکیده
We present an ecofriendly hydroxyapatite (HAP) material functionalized with tin (Sn/HAP) for efficient interfacial reduction of Cr(VI) to Cr(III). Tin was deposited on HAP at different concentrations (from 0.2 1.2 mmol/g) using colloidal or clear acid solutions SnCl2. The morphological and structural properties fresh used Sn/HAP samples were determined (N2 adsorption-desorption, transmission electron microscopy techniques, XRPD, XPS). Tests performed under various conditions: pH 3–7, inert oxidant atmosphere, sample aging (up 15 days). prepared revealed the best performances in Cr(III), carried out mild conditions (40 °C acidified solution) initial concentration range from 25 50 ppm. Best removal (10 mg/g) obtained by a Sn-concentration 0.65 mmol/g complete adsorption formed Cr(III) surface. This finding associated higher Sn-dispersion (surface Sn, 9.4 at.%) compared (surface, Sn 7.7 at.%), as evidenced HAADF-STEM/EDX XPS analyses. Remarkably, tightly retained surface reaction (0.7% leaching), confirming occurrence solid-liquid interphase.
منابع مشابه
Stable chromium isotopes as indicators of reduction and immobilization of hexavalent chromium in groundwater
متن کامل
Microbial Reduction of Hexavalent Chromium
Publication 1. A. Manceau et al, “Quantitative Zn speciation in smelter-contaminated soils by EXAFS spectroscopy,” Am. J. Sci. (in press, 2000). Figure 3 (top) Soil samples were taken at several depths from a contaminated site. (bottom) Model compounds derived from polarized-EXAFS data at the ESRF and μ-EXAFS data at the ALS provide a good fit with powder-EXAFS spectra from a soil sample, there...
متن کاملRemoval of Trivalent and Hexavalent Chromium by Seaweed Biosorbent
Protonated or Ca-form Sargassum seaweed biomass bound up to 40 mg/g of Cr(III) by ion exchange at pH 4. An ion-exchange model assuming that the only species taken up by the biomass was Cr(OH)2+ successfully fitted the experimental biosorption data for Cr(III). The maximum uptake of Cr(VI) by protonated Sargassum biomass at pH 2 was explained by simultaneous anion exchange and Cr(VI) to Cr(III) ...
متن کاملCarcinogenicity of hexavalent chromium.
Hexavalent chromium (Cr(VI)), a commonly used industrial metal, is a well known human lung carcinogen. Epidemiology and animal studies suggest that the particulate Cr(VI) compounds, specifically the water insoluble compounds, are the more potent carcinogens; however, the carcinogenic mechanism remains unknown. Here we summarize recent Cr(VI)-induced human tumour, in vivo, cell culture and in vi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Applied Surface Science
سال: 2021
ISSN: ['1873-5584', '0169-4332']
DOI: https://doi.org/10.1016/j.apsusc.2020.148227