Combination of interfacial reduction of hexavalent chromium and trivalent chromium immobilization on tin-functionalized hydroxyapatite materials

نویسندگان

چکیده

We present an ecofriendly hydroxyapatite (HAP) material functionalized with tin (Sn/HAP) for efficient interfacial reduction of Cr(VI) to Cr(III). Tin was deposited on HAP at different concentrations (from 0.2 1.2 mmol/g) using colloidal or clear acid solutions SnCl2. The morphological and structural properties fresh used Sn/HAP samples were determined (N2 adsorption-desorption, transmission electron microscopy techniques, XRPD, XPS). Tests performed under various conditions: pH 3–7, inert oxidant atmosphere, sample aging (up 15 days). prepared revealed the best performances in Cr(III), carried out mild conditions (40 °C acidified solution) initial concentration range from 25 50 ppm. Best removal (10 mg/g) obtained by a Sn-concentration 0.65 mmol/g complete adsorption formed Cr(III) surface. This finding associated higher Sn-dispersion (surface Sn, 9.4 at.%) compared (surface, Sn 7.7 at.%), as evidenced HAADF-STEM/EDX XPS analyses. Remarkably, tightly retained surface reaction (0.7% leaching), confirming occurrence solid-liquid interphase.

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ژورنال

عنوان ژورنال: Applied Surface Science

سال: 2021

ISSN: ['1873-5584', '0169-4332']

DOI: https://doi.org/10.1016/j.apsusc.2020.148227